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Talc with particle sizes of 1250 mesh (Talc‐1250), 3000 mesh (Talc‐3000), and 5000 mesh (Talc‐5000), used as synergist, was added into transparent fireproof coatings applied in wood substrates, and the influence of talc particle size on the comprehensive properties of the coatings was analyzed carefully. The results show that adding talc exerts super synergistic effect on enhancing the flame retardancy...